Scanning a Silicon Photomultiplier with a Laser Beam

Physics of Particles and Nuclei Letters - The Silicon Photomultiplier (SiPM) is a novel semiconducting photodetector which can detect single photons. It consists of many microcells (pixels)...     

4.50—Polarographic investigation of conformational changes of human serum albumin: Part I. Unfolding of human serum albumin by urea

The mechanism of the unfolding of human serum albumin by urea was studied using d.c. polarography. It was found that this reaction is a complex process which cannot be described in terms of a two-state transition model. As well as the Brdi?ka catalytic current we have also studied the reduction current of disulfide groups in native and denatured human serum albumin. The number of cystine residues accessible for electrode reduction in native and denatured protein was calculated. On the basis of these results a scheme for the unfolding of human serum albumin by urea is proposed.     

Quantum-Chemical Study of the Relative Stability of N-Substituted Tetrazole Isomers

The enthalpies of formation and total energies of a series of 1- and 2-substituted tetrazoles in the gas phase and in solution were calculated by MNDO and AM1 semiempirical methods and by a set of nonempirical procedures. The effect of solvent on the relative stability of N-substituted tetrazoles was estimated in terms of the PCM, SM5, and SCRF models. The possibility for isomerization of N-substituted tetrazoles, depending on the substituent in position 1 or 2, was studied at the MP2/6-31G*//HF/6-31G* level. According to the results of nonempirical calculations, 2-substituted tetrazoles are more stable in the gas phase, in keeping with the experimental data for the corresponding isomers. The solvent nature is an important factor affecting isomerization of N-substituted tetrazoles: Rise in the solvent polarity leads to displacement of the equilibrium toward 1-substituted isomers.     

57Fe Mössbauer study of amorphous and nanocrystalline Fe73.5Nb3Cu1Si13.5B9 after neutron irradiation

⁵⁷Fe Mössbauer spectroscopy is used to study neutron irradiation induced changes in the short-range order of Fe_73.5Nb₃Cu₁Si_13.5B₉ alloy. The samples are investigated in both amorphous and nanocrystalline states. Neutron irradiation leads to an increase of the standard deviation of a hyperfine field distribution (HFD), implying rearrangement of the atoms towards disordering. Simultaneously, changes in the average value of the hyperfine field and a net magnetic moment position occur as a consequence of a spin reorientation, atom mixing and microscopic stress centres which are introduced by neutron irradiation.     

Einstein 4-manifolds and nonpositive isotropic curvature

We give conditions for the linear span of the positive L-weakly compact (resp. M-weakly compact) operators to be a Banach lattice under the regular norm, for that Banach lattice to have an order continuous norm, to be an AL-space or an AM-space.     

On vertex symmetric digraphs

The problem of how “near” we can come to a n-coloring of a given graph is investigated. I.e., what is the minimum possible number of edges joining equicolored vertices if we color the vertices of a given graph with n colors. In its generality the problem of finding such an optimal color assignment to the vertices (given the graph and the number of colors) is NP-complete. For each graph G, however, colors can be assigned to the vertices in such a way that the number of offending edges is less than the total number of edges divided by the number of colors. Furthermore, an Ω(epn) deterministic algorithm for finding such an n-color assignment is exhibited where e is the number of edges and p is the number of vertices of the graph (e?p?n). A priori solutions for the minimal number of offending edges are given for complete graphs; similarly for equicolored K_m in K_p and equicolored graphs in K_p.